Facile use of silver nanoparticles-loaded alumina/silica in nanofluid formulations for enhanced catalytic performance toward 4-nitrophenol reduction

The introduction of toxic chemicals into the environment can result in water pollution leading to the degradation of biodiversity as well as human health. This study presents a new approach of using metal oxides (Al₂O₃ and SiO₂) modified with a plasmonic metal (silver, Ag) nanoparticles (NPs)-based nanofluid (NF) formulation for environmental remediation purposes. Firstly, we prepared the Al₂O₃ and SiO₂ NFs of different concentrations (0.2 to 2.0 weight %) by ultrasonic-assisted dispersion of Al₂O₃ and SiO₂ NPs with water as the base fluid. The thermo-physical (viscosity, activation energy, and thermal conductivity), electrical (AC conductivity and dielectric constant) and physical (ultrasonic velocity, density, refractive index) and stability characteristics were comparatively evaluated. The Al₂O₃ and SiO₂ NPs were then catalytically activated by loading silver NPs to obtain Al₂O₃/SiO₂@Ag composite NPs. The catalytic reduction of 4-nitrophenol (4-NP) with Al₂O₃/SiO₂@Ag based NFs was followed. The catalytic efficiency of Al₂O₃@Ag NF and SiO₂@Ag NF, for the 4-NP catalysis, is compared. Based on the catalytic rate constant evaluation, the catalytic reduction efficiency for 4-NP is found to be superior for 2% weight Al₂O₃@Ag NF (92.9 × 10⁻³ s⁻¹) as compared to the SiO₂@Ag NF (29.3 × 10⁻³ s⁻¹). Importantly, the enhanced catalytic efficiency of 2% weight Al₂O₃@Ag NF for 4-NP removal is much higher than other metal NPs based catalysts reported in the literature, signifying the importance of NF formulation-based catalysis.